Olivia Pope (Kerry Washington), Scandal

There is no one — no one — on the Hill whose appearance is as polished as Olivia Pope’s. As a professional fixer, she needs to be decisive, and that’s reflected in her outfits, which lean toward a monochromatic palette — lots of white, gray and black. Olivia’s go-to pieces are her white trenchcoat and pantsuits that make a bold statement that always says she’s in charge and will wear the white hat … sometimes literally!